Testing perovskite and tandem cells: preconditioning, spectrum, time

Perovskite and tandem devices are metastable: their performance depends on the light history before the measurement. Accurate testing needs steady-state preconditioning, a long measurement pulse, and per-wavelength spectral control for current-matching tandem junctions, the combination the Avalon Nexun Perovskite and Nexun ULTRA were built for.

A perovskite cell does not have one efficiency; it has a state. Ion migration and trap dynamics mean the device you measure depends on the seconds to minutes of illumination before the sweep. Measure cold and you under-read; soak uncontrolled and you over-read. The instrument has to control light history, not just light quality.

Preconditioning is part of the measurement

The Nexun Perovskite integrates steady-state preconditioning with the 500 ms measurement pulse on one bench: the cell is held under defined irradiance until it stabilises, then measured in a single long sweep, with the whole sequence scripted and logged. For long-soak protocols and light-induced degradation studies, the steady-state Nexun Steady holds full-spectrum irradiance indefinitely.

Tandems add a spectral problem

A two-terminal tandem is current-limited by whichever junction sees less of its light. Measuring it honestly means setting the spectral balance per band, which is exactly what per-wavelength LED control provides. The Nexun ULTRA switches 37 wavelengths individually in software, so junction-by-junction characterisation and current-matching studies run on the same instrument as the certification measurement. For space multi-junction work, the Nexun Cosmo extends the range to 300 to 1900 nm under AM0.

What a defensible perovskite number requires

  • Scripted steady-state preconditioning, logged with the measurement.
  • A 500 ms single-sweep pulse so the metastable state is not disturbed mid-curve.
  • Per-wavelength spectral control for tandem current matching.
  • A stabilisation criterion (MPP tracking until drift falls below threshold), not a fixed soak time.

Frequently asked questions

What solar simulator do I need for perovskite cells?
One that combines steady-state preconditioning with a long (≈500 ms) measurement pulse on the same bench, so the cell's metastable state is stabilised and then measured in a single sweep. The Avalon Nexun Perovskite is built around exactly this sequence.
Why do perovskite cells need preconditioning before IV measurement?
Their performance depends on illumination history through ion migration and trap filling. Without a defined stabilisation under light, the measured efficiency reflects an arbitrary transient state rather than the device's operating performance.
How do you measure a perovskite-silicon tandem accurately?
Current-match the junctions with per-wavelength spectral control, precondition to a stabilised state, then sweep once over ~500 ms. The Nexun ULTRA's 37 individually switchable wavelengths make the spectral part a software setting.
What is the difference between flash and steady-state testing for perovskites?
Flash (long-pulse) testing measures a stabilised device quickly and is the certification workhorse; steady-state testing holds irradiance indefinitely for soak, MPP-tracking and degradation protocols. A complete perovskite lab uses both, e.g. Nexun Perovskite plus Nexun Steady.
Related products
Nexun PerovskiteNexun SteadyNexun ULTRA
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